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This can be resolved by seeking absolution at the Church of Vows. Be warned, attacking Sellen here can cause issues with her availability as a merchant elsewhere and stall progression in her quest line.
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After defeating the boss, the Site of Grace "Waypoint Ruins Cellar" appears in their boss room, allowing easy access to Sellen's services. Players can reach her after defeating the Mad Pumpkin Head.
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She can be found inside the Waypoint Ruins, far east from where you first arrive in Limgrave. Sorceress Sellen is a Merchant and NPC in Elden Ring.
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